The construction of a ZnO/SnO2 heterostructure is considered in the literature as an efficient strategy to improve photocatalytic properties of ZnO due to an electron/hole delocalisation process. This study is dedicated to an investigation of the photocatalytic performance of ZnO/SnO2 heterostructures directly synthesized in macroporous glass fibres membranes. Hydrothermal ZnO nanorods have been functionalized with SnO2 using an atomic layer deposition (ALD) process. The coverage rate of SnO2 on ZnO nanorods was precisely tailored by controlling the number of ALD cycles. We highlight here the tight control of the photocatalytic properties of the ZnO/SnO2 structure according to the coverage rate of SnO2 on the ZnO nanorods. We show that the highest degradation of methylene blue is obtained when a 40% coverage rate of SnO2 is reached. Interestingly, we also demonstrate that a higher coverage rate leads to a full passivation of the photocatalyst. In addition, we highlight that 40% coverage rate of SnO2 onto ZnO is sufficient for getting a protective layer, leading to a more stable photocatalyst in reuse.